1,4-Hydroboration Reactions of Electron-Poor Aromatic Rings by N‑Heterocyclic Carbene Boranes

1,4-Hydroboration Reactions of Electron-Poor Aromatic Rings by N‑Heterocyclic Carbene Boranes

Reactions of N-heterocyclic carbene boranes (NHC-boranes) with electron-poor aromatic rings under photoredox conditions provide dearomatized 3-NHC-boryl-1,5-cycohexadienes, which are formally products of 1,4-hydroboration reactions. When regioisomers are possible, the more crowded (doubly ortho-subs...

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Autore principale: Wen Dai (1607932) (author)
Altri autori: Steven J. Geib (1328757) (author), Dennis P. Curran (1330713) (author)
Pubblicazione: 2020
Soggetti:
Biochemistry
Molecular Biology
Physiology
Biotechnology
Evolutionary Biology
Developmental Biology
Marine Biology
Cancer
Infectious Diseases
Environmental Sciences not elsewhere classified
Chemical Sciences not elsewhere classified
Electron-Poor Aromatic Rings
N-heterocyclic carbene boranes
NHC-borane
electron-poor
NHC-boryl
regioselective protonation
photoredox conditions
cyclohexadienyl anion
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