N‑Heterocyclic Carbene (NHC) Ligand Exchange of Bis(NHC)–Pd(II) Complexes

N‑Heterocyclic Carbene (NHC) Ligand Exchange of Bis(NHC)–Pd(II) Complexes

N-heterocyclic carbene (NHC)–Pd(II) bonds are recognized as rather robust bonds to equip palladium(II) centers with decent stability and stereoelectronic tunability. In this report, the authentic carbene–Pd(II) bonds in <i>N</i>-ammonium- and sulfonate-functionalized NHC complexes were a...

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Bibliographic Details
Main Author: Qiaoqiao Teng (1387554) (author)
Other Authors: Wei Liu (20030) (author), Yaru Zhao (2161255) (author), Lina Zhang (112887) (author), Hao Jin (326533) (author), Qi Meng (262900) (author), Gilles Frison (1278360) (author)
Published: 2024
Subjects:
Biophysics
Biochemistry
Cell Biology
Molecular Biology
Neuroscience
Cancer
Environmental Sciences not elsewhere classified
Chemical Sciences not elsewhere classified
electrostatic interactions play
combined experimental studies
afford four well
zwitterionic heterobiscarbene complexes
resulting zwitterionic complexes
nhc )– pd
functionalized nhc complexes
rather robust bonds
nhc ligand exchange
ligand exchange
complexes n
exchange appears
stereoelectronic tunability
n </
minimal role
heterocyclic carbene
equip palladium
driven primarily
decent stability
>- ammonium
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