Chiral Dysprosium-[7]Helicene Macrocycles Showing Record Single-Molecule Magnet Properties in the Lanthanide–Helicene Family

Chiral helicene-based metal complexes have emerged as an extremely promising class of multifunctional molecules for a wide range of applications. Despite significant progress in the synthesis of helicene-based transition-metal complexes in recent decades, lanthanide species lag far behind and their...

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書誌詳細
第一著者:	Zhenhua Zhu (3158175) (author)
その他の著者:	Tingting Wang (123983) (author), Lorenzo A. Mariano (20870567) (author), Sagar Paul (18989635) (author), Wolfgang Wernsdorfer (1332453) (author), Alessandro Lunghi (2866130) (author), Jinkui Tang (1406413) (author)
出版事項:	2025
主題:	Biophysics Biochemistry Pharmacology Biotechnology Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified third kramers doublet still largely underexplored phonon analysis reveal extremely promising class equatorial benzene rings despite significant progress >- diaxial manner open hysteresis loops spin relaxation dynamics helicene enantiomers using 12 k using based metal complexes molecule magnet properties molecule magnet metal complexes 12 k hysteresis closure based transition zero field wide range u </ trans </ traditional metrics sweep rate recent decades raman relaxation orbach relaxation modulating magnetodynamics magnetization via instead driven findings pave chiroptical effects chiral dy axial ligand also land >< sub 200 oe
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Chiral Dysprosium-[7]Helicene Macrocycles Showing Record Single-Molecule Magnet Properties in the Lanthanide–Helicene Family

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