Construction of Acyclic Vicinal All-Carbon Quaternary and Tertiary Carbon Stereocenters via a Stereoselective Claisen Rearrangement
The selective construction of neighboring congested stereocenters in an acyclic setting bearing an all-carbon quaternary stereocenter is one of the important challenges in stereoselective synthesis. [3,3]-Sigmatropic rearrangements are powerful reactions with potential for the stereoselective constr...
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2025
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