Synthesis and Characterization of Ruthenium and Osmium Metal–Organic Frameworks with a Pyrazine Ligand: Two-Dimensional Analogues of the Creutz–Taube Ion

The Creutz–Taube ion, [(NH3)5RuII(μ-pz)RuIII(NH3)5]5+ (pz = pyrazine) is a prominent example of multinuclear Ru systems, which exists in a...

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Bibliographic Details
Main Author:	Wang Zhang (289732) (author)
Other Authors:	Hiroyoshi Ohtsu (1927960) (author), Hiroaki Suzuki (574019) (author), Akimitsu Shimizu (20499826) (author), Terumasa Shimada (10104893) (author), Kiyohiro Adachi (6858965) (author), Daisuke Hashizume (1419916) (author), Jin Young Koo (1414141) (author), Hee Cheul Choi (1275738) (author), Yuki Wada (6078326) (author), Pavel M. Usov (4566745) (author), Masaki Kawano (1414144) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Medicine Genetics Neuroscience Developmental Biology Cancer Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified ray diffraction techniques ray absorption spectroscopy previous research efforts layered framework structure free synthetic methodologies valent ru complexes ray scattering confirmed 5 +</ sup 5 </ sub 2 </ sub pz ) ru multinuclear ru systems n </ ru coordination ></ sub valence states semiconductor range samples reaching resultant materials prominent example optimize crystallinity mof ). metal centers findings expand established chemistry electronic delocalization dimensional analogues conductivity values [( nh
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