Synthesis and Characterization of Ruthenium and Osmium Metal–Organic Frameworks with a Pyrazine Ligand: Two-Dimensional Analogues of the Creutz–Taube Ion

Synthesis and Characterization of Ruthenium and Osmium Metal–Organic Frameworks with a Pyrazine Ligand: Two-Dimensional Analogues of the Creutz–Taube Ion

The Creutz–Taube ion, [(NH<sub>3</sub>)<sub>5</sub>Ru<sup>II</sup>(μ-pz)­Ru<sup>III</sup>(NH<sub>3</sub>)<sub>5</sub>]<sup>5+</sup> (pz = pyrazine) is a prominent example of multinuclear Ru systems, which exists in a...

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محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Wang Zhang (289732) (author)
مؤلفون آخرون: Hiroyoshi Ohtsu (1927960) (author), Hiroaki Suzuki (574019) (author), Akimitsu Shimizu (20499826) (author), Terumasa Shimada (10104893) (author), Kiyohiro Adachi (6858965) (author), Daisuke Hashizume (1419916) (author), Jin Young Koo (1414141) (author), Hee Cheul Choi (1275738) (author), Yuki Wada (6078326) (author), Pavel M. Usov (4566745) (author), Masaki Kawano (1414144) (author)
منشور في: 2025
الموضوعات:
Biophysics
Biochemistry
Medicine
Genetics
Neuroscience
Developmental Biology
Cancer
Chemical Sciences not elsewhere classified
Physical Sciences not elsewhere classified
ray diffraction techniques
ray absorption spectroscopy
previous research efforts
layered framework structure
free synthetic methodologies
valent ru complexes
ray scattering confirmed
5 +</ sup
5 </ sub
2 </ sub
pz )­ ru
multinuclear ru systems
n </
ru coordination
></ sub
valence states
semiconductor range
samples reaching
resultant materials
prominent example
optimize crystallinity
mof ).
metal centers
findings expand
established chemistry
electronic delocalization
dimensional analogues
conductivity values
[( nh
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