Bismuth Radical Catalysis: Thermally Induced Intramolecular C(sp<sup>3</sup>)–C(sp) Cyclization of Unactivated Alkyl Iodides and Alkynes

Bismuth Radical Catalysis: Thermally Induced Intramolecular C(sp<sup>3</sup>)–C(sp) Cyclization of Unactivated Alkyl Iodides and Alkynes

Bismuth radical chemistry has attracted increased interest in recent years. Here, we report a series of bismuth–manganese complexes that catalyze the intramolecular redox-neutral coupling of alkyl iodides and alkynes under purely thermal conditions. Computational studies support the design of cataly...

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Bibliographic Details
Main Author: Sebastián Martínez (12915438) (author)
Other Authors: Marius A. Junghanns (22048866) (author), Tobias Dunaj (22048869) (author), Crispin Lichtenberg (1519525) (author)
Published: 2025
Subjects:
Biophysics
Biochemistry
Medicine
Biological Sciences not elsewhere classified
Chemical Sciences not elsewhere classified
purely thermal conditions
including drug derivatives
computational studies support
attracted increased interest
bismuth radical catalysis
unactivated alkyl iodides
alkyl iodides
radical nature
underexplored mode
recent years
neutral coupling
intramolecular redox
catalyst candidates
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