Bismuth Radical Catalysis: Thermally Induced Intramolecular C(sp<sup>3</sup>)–C(sp) Cyclization of Unactivated Alkyl Iodides and Alkynes
Bismuth radical chemistry has attracted increased interest in recent years. Here, we report a series of bismuth–manganese complexes that catalyze the intramolecular redox-neutral coupling of alkyl iodides and alkynes under purely thermal conditions. Computational studies support the design of cataly...
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2025
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