Revisiting CNC<sub>6</sub>F<sub>5</sub>: The Quest for Isocyanide Ligands with Strong π‑Acceptor Properties Evaluated by Energy Decomposition Analysis

Revisiting CNC<sub>6</sub>F<sub>5</sub>: The Quest for Isocyanide Ligands with Strong π‑Acceptor Properties Evaluated by Energy Decomposition Analysis

While perfluorinated isocyanide ligands such as CNCF<sub>3</sub> and CNC<sub>6</sub>F<sub>5</sub> have been known for decades, their use by organometallic chemists has been limited primarily due to the challenges associated with their cumbersome synthesis. In this...

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Bibliographic Details
Main Author:	Tim-Niclas Streit (9673854) (author)
Other Authors:	Robin Sievers (19869795) (author), Malte Sellin (9545967) (author), Moritz Malischewski (1469212) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Medicine Cell Biology Molecular Biology Pharmacology Biotechnology Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified negative oxidation states limited primarily due improved synthetic route isoelectronic metal fragments 6 </ sub 5 </ sub 4 </ sub 3 </ sub 2 </ sub also included ligands acceptor abilities reveal stabilize metal centers energy decomposition analysis co )< sub perfluorinated isocyanide ligands metal centers isocyanide ligands p </ perfluorinated counterparts carbonyl ligands acceptor properties structural characterization strong binding resulting complexes pronounced effects potential suitability organometallic chemists nocv method minor differences cumbersome synthesis charged complexes challenges associated analyzed using
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